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Compound - 4S5S-cruentol [(4S,5S)-5-Methyloctan-4-ol]

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(4S,5S)-5-Methyloctan-4-ol Formula:  C9H20O  CAS#:    MW:  144.25  [MS]  [ NMR ]  [Behavioural function]

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Reference(s) for synthesis of (4S,5S)-5-Methyloctan-4-ol [4S5S-cruentol] Le Bel, N.A., Liesemer, R.N., and Mehmedbasich, E. 1963. The stereochemistry of additions to olefins. III. The prins reaction with cis- and trans-4-octene. J. Org. Chem. 28:615-620.   Levesque, G., and Pinazzi, C. 1971. Bull. Soc. Chim. Fr. 1008-1010.   Odriozola, J.M., García, J.M., González, A., and Gil, P. 1999. Asymmetric synthesis of phoenicol, ferrugineol and cruentol, aggregation pheromones of Rhynchophorus spp.Tetrahedron: Asymmetry. 10:4627-4632.   Shanmugam, P., and Miyashita, M. 2003. R3Al-R'3SiOTf: novel and powerful reagent system for stereospecific alkylation-silylation reactions of epoxides. Org. Lett. 18:3265-3268.   Weissling, T.J., Giblin Davis, R.M., Gries, G., Gries, R., Perez, A.L., Pierce, H.D., Jr., and Oehlschlager, A.C. 1994. Aggregation pheromone of palmetto weevil, Rhynchophorus cruentatus (F.) (Coleoptera: Curculionidae). J. Chem. Ecol. 20:505-515.