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Compound - S,S-epianastrephin [(3aS,4S,7aS)-4,7a-Dimethyl-4-vinylhexahydrobenzofuran-2(3H)-one]

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(3aS,4S,7aS)-4,7a-Dimethyl-4-vinylhexahydrobenzofuran-2(3H)-one Formula:  C12H18O2  CAS#:  77670-93-0  MW:  194.27  [MS]  [ NMR ]  [ Kovats ]  [Behavioural function]

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Reference(s) for synthesis of (3aS,4S,7aS)-4,7a-Dimethyl-4-vinylhexahydrobenzofuran-2(3H)-one [S,S-epianastrephin] Saito, A., Matsushita, H., and Kaneko, H. 1984. Synthesis of (±)-anastrephin and (±)-epianastraphin. Chem. Lett. 729-730.   Schultz, A.G., and Kirincich, S.J. 1996. Asymmetric total synthesis of the Caribbean fruit fly pheromone (+)-epianastrephin. J. Org. Chem. 61:5626-5630.   Strekowski, L, Visnick, M., and Battiste, M.A. 1983. A highly efficient and convenient lactonization prodedure for strained trans-fused lactones. Synthesis. 6:493-494.   Vecchio, G.H.-D., and Oehlschlager, A.C. 1994. Stereospecific synthesis of suspensolide, a male-produced pheromone of the Caribbean fruit fly, Anastrepha suspensa (Loew), and the Mexican fruit fly, Anastrepha ludens (Loew). J. Org. Chem. 59:4853-4857.