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Compound - verbenone [4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-one]

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4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-one Formula:  C10H14O  CAS#:  80-57-9  MW:  150.22  [MS]  [ NMR ]  [ Kovats ]  [Behavioural function]  [Occurrence in flower]

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Reference(s) for synthesis of 4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-one [verbenone] Carlsen, P.H.J., Husbyn, M., Braenden, J.E., and Eliason, R. 1989. Acta Chem. Scand. 43:485-488.   Hurst, J.J., and Whitham, G.H. 1960. The photochemistry of verbenone. J. Chem. Soc. 2864-2869.   Lajunen, M., and Koskinen, A.M.P. 1994. Co(II)-catalysed allylic oxidation of alpha-pinene by molecular oxygen; synthesis of verbenone. Tetrahedron Lett. 35:4461-4464.   Pearson, A.J., Chen, Y.-S., Hsu, S.-Y., and Ray, T. 1984. Oxidation of alkenes to enones using tert-butyl hydroperoxide in the presence of chromium carbonyl catalysts. Tetrahedron Lett. 25:1235-1238.   Weber, L., Behling, J., Haufe, G., and Hennig, H. 1992. Photokatalytische oxygenierung von cycloalkenen mit mangan(III) tetraarylporphyrin-komplexen. J. Prakt. Chem. 334:265-268.